Category: indole-building-block. Ito, S; Kitamura, T; Arulmozhiraja, S; Manabe, K; Tokiwa, H; Suzuki, Y in [Ito, Saki; Suzuki, Yumiko] Sophia Univ, Fac Sci & Technol, Dept Mat & Life Sci, Chiyoda Ku, 7-1 Kioicho, Tokyo 1028554, Japan; [Kitamura, Taiki; Manabe, Kei] Univ Shizuoka, Sch Pharmaceut Sci, Suruga Ku, 52-1 Yada, Shizuoka 4228526, Japan; [Arulmozhiraja, Sundaram; Tokiwa, Hiroaki] Rikkyo Univ, Dept Chem, Toshima Ku, 3-34-1 Nishi Ikebukuro, Tokyo 1718501, Japan; [Arulmozhiraja, Sundaram; Tokiwa, Hiroaki] Rikkyo Univ, Res Ctr Smart Mol, Toshima Ku, 3-34-1 Nishi Ikebukuro, Tokyo 1718501, Japan published Total Synthesis of Termicalcicolanone A via Organocatalysis and Regioselective Claisen Rearrangement in 2019.0, Cited 29.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
A total synthesis of an anticancer xanthone natural product termicalcicolanone A utilizing multiple nucleophilic aromatic substitutions and pericyclic reactions has been developed. The pyrano[3,2-b]xanthen-6-one scaffold was constructed via NHC-catalyzed aroylation to produce the benzophenone intermediate, Claisen cyclization to form the pyran ring, and intramolecular 1,4-addition to construct the xanthone framework. The prenyl group was introduced in the final stages of the synthesis through regioselective Claisen rearrangement. The synthesis has been achieved in 19 steps.
About Benzyl Alcohol, If you have any questions, you can contact Ito, S; Kitamura, T; Arulmozhiraja, S; Manabe, K; Tokiwa, H; Suzuki, Y or concate me.. Category: indole-building-block
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles