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The amide functionality was used as a remote control for the stereoselective hydro-heteroarylation of acrylamides. This gold-catalyzed carbocyclization provides a diversity-oriented and concise route to biologically important pyrido[3,4-b]indoles. Moreover, the adverse effect of silver salts on this hydro-heteroarylation was also studied.
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Reference：
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles