Product Details of 150-19-6. Patel, JJ; Blackburn, T; Alessi, M; Sawinski, H; Snieckus, V in [Patel, Jignesh J.; Blackburn, Thomas; Alessi, Manlio; Sawinski, Hannah; Snieckus, Victor] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada published Tetraethylphosphorodiamidate-Directed Metalation Group: Directed Ortho and Remote Metalation, Cross Coupling, and Remote Phospha Anionic Fries Rearrangement Reactions in 2020.0, Cited 70.0. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6.
The linked directed ortho and remote metalation (DoM and DreM) and cross-coupling reactions of aryl phosphorodiamidates (Ar-OP(O)(NEt2)(2)) is reported. The o-iodo and o-boronato aryl tetraethylphosphorodiamidates 3, prepared by DoM, undergo orthogonal Ni- and Pd-catalyzed Suzuki-Miyaura cross coupling to furnish biaryls 4 and 5 in good to excellent yields. Silicon group protection of biaryl 4 via DoM followed by previously unobserved DreM phospha anionic Fries rearrangement affords biaryls 11 which, under acidic conditions, furnish oxaphosphorine oxides 12.
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Reference:
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