Authors Lei, K; Li, P; Yang, XF; Wang, SB; Wang, XK; Hua, XW; Sun, B; Ji, LS; Xu, XH in AMER CHEMICAL SOC published article about ACID-DERIVATIVES; ANTIMICROBIAL ACTIVITY; CRYSTAL-STRUCTURE; TRIKETONE; ARABIDOPSIS; INHIBITORS; DISCOVERY in [Lei, Kang; Li, Pan; Wang, Shi-Ben; Wang, Xue-Kun; Hua, Xue-Wen; Sun, Bin; Ji, Lu-Sha] Liaocheng Univ, Sch Pharm, Liaocheng 252059, Shandong, Peoples R China; [Lei, Kang; Hua, Xue-Wen; Sun, Bin; Xu, Xiao-Hua] Nankai Univ, Inst Elementoorgan Chem, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China; [Yang, Xue-Fang] Shanxi Agr Univ, Coll Agr, Jinzhong 030800, Shanxi, Peoples R China in 2019.0, Cited 37.0. Recommanded Product: m-Methoxyphenol. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6
In order to develop a novel herbicide containing the beta-triketone motif, a series of 4-hydroxyl-3-(2-phenoxyacetyl)-pyran-2-one derivatives were designed and synthesized. The bioassay results showed that compound II15 had good pre-emergent herbicidal activity even at a dosage of 187.5 g ha(-1). Moreover, compound II15 showed a broader spectrum of weed control when compared with a commercial herbicide 2,4-dichlorophenoxyacetic acid (2,4-D), and displayed good crop safety to Triticum aestivum L. and Zea mays Linn. when applied at 375 g ha(-1) under pre-emergence conditions, which indicated its great potential as a herbicide. More importantly, studying the molecular mode of action of compound II15 revealed that the novel triketone structure is a proherbicide of its corresponding phenoxyacetic acid auxin herbicide, which has a herbicidal mechanism similar to that of 2,4-D. The present work indicates that the 4-hydroxyl-3-(2-phenoxyacetyl)-pyran-2-one motif may be a potential lead structure for further development of novel auxin-type herbicides.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles