An article Regio- and diastereoselective Pd-catalyzed aminochlorocyclization of allylic carbamates: scope, derivatization, and mechanism WOS:000658407700001 published article about UNACTIVATED ALKENES; HYDROGEN-PEROXIDE; INTERMOLECULAR AMINOACETOXYLATION; INTRAMOLECULAR CHLOROAMINATION; OXIDATIVE CYCLIZATION; PALLADIUM; DIAMINATION; ALCOHOLS; DIFUNCTIONALIZATION; AMINOPALLADATION in [Papa Spadafora, Bruna; Matsushima, Jullyane Emi; Ariga, Elaine Miho; Soares, Priscila Machado Arruda; de Oliveira-Silva, Diogo; Vinhato, Elisangela; Rodrigues, Alessandro] Univ Fed Sao Paulo, Dept Chem, UNIFESP Prof Artur Riedel St 275,Lab 10, BR-09972270 Diadema, SP, Brazil; [Moreira Ribeiro, Francisco Wanderson] Univ Sao Paulo, Inst Chem, Dept Fundamental Chem, Av Prof Lineu Prestes 748, BR-05508000 Sao Paulo, SP, Brazil; [Moreira Ribeiro, Francisco Wanderson; Omari, Isaac; McIndoe, J. Scott] Univ Victoria, Dept Chem, POB 3065, Victoria, BC V8W 3V6, Canada in 2021, Cited 99. Name: 4-Methoxybenzaldehyde. The Name is 4-Methoxybenzaldehyde. Through research, I have a further understanding and discovery of 123-11-5
The regio- and diastereoselective synthesis of oxazolidinones via a Pd-catalyzed vicinal C-N/C-Cl bond-forming reaction from internal alkenes of allylic carbamates is reported. The oxazolidinones are obtained in yields of 44 to 95% with high to excellent diastereoselectivities (from 6 : 1 to >20 : 1 dr) from readily available precursors. This process is scalable, and the products are suitable for the synthesis of useful amino alcohols. A detailed theoretical and experimental mechanistic study was carried out to describe that the reaction proceeds through an anti-aminopalladation of the alkene followed by an oxidative C-Pd(ii) cleavage with retention of the carbon stereochemistry to yield the major diastereomer. The role of Cu(ii) in a C-Cl bond-forming mechanism step has also been proposed.
Name: 4-Methoxybenzaldehyde. Welcome to talk about 123-11-5, If you have any questions, you can contact Spadafora, BP; Ribeiro, FWM; Matsushima, JE; Ariga, EM; Omari, I; Soares, PMA; de Oliveira-Silva, D; Vinhato, E; McIndoe, JS; Correra, TC; Rodrigues, A or send Email.
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Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles