An article Palladium-Catalyzed Enantioselective 7-exo-Trig Carbopalladation/Carbonylation: Cascade Reactions To Achieve Atropisomeric Dibenzo[b,d]azepin-6-ones WOS:000649477300077 published article about CYCLIZATION-CARBONYLATION; HECK REACTION; DIBENZAZEPINONES; INHIBITORS; ARYLATION in [Hu, Huaanzi; Peng, Yan; Yu, Ting; Cheng, Sidi; Luo, Shuang; Zhu, Qiang] Chinese Acad Sci, Guangzhou Inst Biomed & Hlth, State Key Lab Resp Dis, Guangzhou 510530, Peoples R China; [Hu, Huaanzi; Peng, Yan; Yu, Ting; Cheng, Sidi; Luo, Shuang; Zhu, Qiang] Univ Chinese Acad Sci, Beijing 100049, Peoples R China; [Luo, Shuang; Zhu, Qiang] Bioland Lab, Guangzhou 510005, Peoples R China; [Zhu, Qiang] Nanning Normal Univ, Coll Chem & Mat, Guangxi Key Lab Nat Polymer Chem & Phys, Nanning 530001, Peoples R China in 2021, Cited 50. The Name is 4-Methoxybenzaldehyde. Through research, I have a further understanding and discovery of 123-11-5. Recommanded Product: 4-Methoxybenzaldehyde
Enantioselective 7-exo-trig cyclocarbopalladation-initiated carbonylation cascade reactions, leading to seven-membered dibenzo[b,d]azepin-6-ones containing a thermodynamically controlled stereogenic axis, have been realized for the first time. A series of 7-acetate- or 7-acetamide-substituted dibenzo[b,d]azepin-6-ones are obtained under atmospheric pressure of CO in good yields with excellent diastereo- and enantioselectivities. The calculated energy difference between the diastereoisomers generated from the stereogenic biaryl axis and the stereogenic center is approximately 2.8 kcal/mol, which agrees with the excellent diastereoselectivity observed.
Recommanded Product: 4-Methoxybenzaldehyde. Welcome to talk about 123-11-5, If you have any questions, you can contact Hu, HAZ; Peng, Y; Yu, T; Cheng, SD; Luo, S; Zhu, Q or send Email.
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Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles