The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)methane, is researched, Molecular C19H18N2O2, CAS is 132098-59-0, about Bis(oxazoline)copper Complexes Covalently Bonded to Insoluble Support as Catalysts in Cyclopropanation Reactions, the main research direction is oxazoline copper complex mercaptopropyl functionalized silica catalyst; vinylbenzyl oxazoline polymer complexation copper heterogeneous catalyst; cyclopropanation supported catalyst copper polymer complex; styrene ethyl diazoacetate cyclopropanation copper complex catalyst.COA of Formula: C19H18N2O2.
Chiral bis(oxazolines) were dialkylated at the methylene bridge, opening the way to immobilization at that position, keeping the C2 symmetry of the chiral ligand. Bis(oxazolines) functionalized with two allyl or vinylbenzyl groups were then grafted onto mercaptopropyl-functionalized silica. The ligands were also immobilized as homopolymers or as styrene-divinylbenzene-vinylbenzyloxazoline copolymers and complexation. The Cu(OTf)2 complexes of the immobilized ligands were used as catalysts in enantioselective cyclopropanation of styrene with Et diazoacetate. The catalyst activity is dependent both on the type of polymer and ligand; the highest activity was attained when using homopolymers and bis(oxazoline) containing indan groups on silica and polymer supports. Bis(oxazoline) bearing tert-Bu groups showed good enantioselectivity only when supported on homopolymers. Some of the heterogeneous catalysts can be easily recovered and reused, as many as five times, with the same yield and stereoselectivity.
There is still a lot of research devoted to this compound(SMILES：C1(CC2=N[C@@H](C3=CC=CC=C3)CO2)=N[C@@H](C4=CC=CC=C4)CO1)COA of Formula: C19H18N2O2, and with the development of science, more effects of this compound(132098-59-0) can be discovered.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles