Final Thoughts on Chemistry for 141556-42-5

This literature about this compound(141556-42-5)COA of Formula: C21H24N2has given us a lot of inspiration, and I hope that the research on this compound(1,3-Bis(2,4,6-trimethylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene) can be further advanced. Maybe we can get more compounds in a similar way.

So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Guthardt, Robin; Mellin, Johanna; Bruhn, Clemens; Siemeling, Ulrich researched the compound: 1,3-Bis(2,4,6-trimethylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene( cas:141556-42-5 ).COA of Formula: C21H24N2.They published the article 《1,1′-Ferrocenylene-Bridged Bis(N-Heterocyclic Olefin) Derivatives》 about this compound( cas:141556-42-5 ) in European Journal of Inorganic Chemistry. Keywords: crystal structure mol ferrocenyl heterocyclic olefin derivative preparation electrochem; ferrocene heterocyclic olefin dimesitylimidazolinylidene diisopropylphenylimidazolinylidene preparation diastereoisomer structure. We’ll tell you more about this compound (cas:141556-42-5).

The 1,1′-ferrocenylene (fc)-bridged bis(N-heterocyclic olefin) compounds (IMes:CH)2fc (1, IMes = 1,3-dimesitylimidazolin-2-ylidene) and (IPr:CH)2fc (2, IPr = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) were synthesized from (ICH2)2fc (3) and the resp. N-heterocyclic carbene IMes or IPr. Ligand substitution reactions of 1 and 2 with [BH3(THF)] afforded the complexes [1(BH3)2] and [2(BH3)2] as mixtures of the rac- and meso-diastereomers. The new ferrocene derivatives 1-3 and the complexes meso-[1(BH3)2], rac-[1(BH3)2] and rac-[2(BH3)2] were structurally characterized by single-crystal x-ray diffraction. 1 And 2 represent a new class of ferrocene-based, and hence redox-active, bidentate ligands. The presence of three redox-active moieties, viz. the ferrocene unit and the two NHO units, is reflected by three consecutive oxidations according to an electrochem. investigation exemplarily performed with 2 by cyclic voltammetry.

This literature about this compound(141556-42-5)COA of Formula: C21H24N2has given us a lot of inspiration, and I hope that the research on this compound(1,3-Bis(2,4,6-trimethylphenyl)-1,3-dihydro-2H-imidazol-2-ylidene) can be further advanced. Maybe we can get more compounds in a similar way.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles