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A unique copper-catalyzed cross-coupling reaction by hydrogen (H 2) removal for the stereoselective synthesis of 3-phosphoindoles
The first Cu(i)-catalyzed cross-coupling reaction by hydrogen (H 2) removal for the stereoselective synthesis of 3-phosphoindoles is reported. Going beyond the oxidative dehydrogenative coupling reactions reported recently, this reaction completely omits the oxidant and base, producing hydrogen (H2) as the only byproduct. the Partner Organisations 2014.
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Reference£º
Indole alkaloid derivatives as building blocks of natural products from?Bacillus thuringiensis?and?Bacillus velezensis?and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles