Synthetic Route of C11H9N. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: 2-Phenylpyridine, is researched, Molecular C11H9N, CAS is 1008-89-5, about Site-Selective Direct C-H Pyridylation of Unactivated Alkanes by Triplet Excited Anthraquinone. Author is Lee, Wooseok; Jung, Sungwoo; Kim, Minseok; Hong, Sungwoo.
Site-selective C-H functionalization in chem. feedstocks were a challenging and useful reaction in the broad field of chem. research. Here, reported a modular photochem. platform for the site-selective C-H pyridylation of unactivated hydrocarbons via the unique synergistic effects of triplet excited anthraquinone and an amidyl radical-based reverse hydrogen atom transfer (RHAT) agent. The selective pyridylation of tertiary and secondary C(sp3)-H bonds in abundant chem. feedstocks was achieved by employing various N-aminopyridinium salts in a highly selective fashion, which provided a new catalytic system for the direct construction of high-value-added compounds under ambient reaction conditions. Moreover, the above operationally simple protocol was applicable to a variety of linear-, branched-, and cyclo-alkanes and more complex mols. with high degrees of site selectivity under visible-light conditions, which provided rapid and straightforward access to versatile synthons for upgrading feedstocks under mild, metal-free reaction conditions.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles