Safety of 2-(Pyridin-4-yl)-1H-benzo[d]imidazole. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: 2-(Pyridin-4-yl)-1H-benzo[d]imidazole, is researched, Molecular C12H9N3, CAS is 2208-59-5, about A series of 1D-to-3D zinc coordination polymers based on the rigid aromatic multicarboxylate ligands and different N-donor ligands: Synthesis, structures, and photoluminescent properties. Author is Sun, Wei; Liu, Jingjuan; Liu, Houting; Liu, Zhiliang.
A novel series of zinc coordination polymers, namely, {[Zn(H2btca)(bpt)]·H2O}n (1), {Zn2(btca)(PyBIm)(H2O)}n (2) and {[Zn1.5(Hbtca)(pytpy)]·H2O}n (3), were assembled using zinc nitrates, an conjugated carboxylate ligand H4btca and different N-donor ligands under hydrothermal conditions (H4btca = 1,1′-biphenyl-2,3,3′,5′-tetracarboxylic acid, bpt = 1H-3,5-bis(4-pyridyl)-1,2,4-triazole, PyBIm = 2-(4-pyridyl)benzimidazole, pytpy = 2,4,6-tris(4-pyridyl)pyridine). Single crystal x-ray diffractions conformed that the three compounds are 1-D beaded chain-like structure, 2-D layered network and 3-D porous structures, resp. The diverse architectures are derived from the different N-donor ligands used during the self-assembling process. Elemental anal., IR spectra and luminescence of all the coordination polymers also were studied. The diverse structures display different luminescence properties. This result extends the relation between the structures and luminescence properties.
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