Mazaud, Louis; Tricoire, Maxime; Bourcier, Sophie; Cordier, Marie; Gandon, Vincent; Auffrant, Audrey published an article about the compound: Nickel(II) chloride ethylene glycol dimethyl ether complex( cas:29046-78-4,SMILESS:COCCOC.Cl[Ni]Cl ).Related Products of 29046-78-4. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:29046-78-4) through the article.
The synthesis of a tridentate NNN ligand incorporating an amidoquinoline and an iminophosphorane (LRH, R = Ph, Cy) was carried out. Coordination to Pd(II) and Ni(II) precursors gave as expected square planar complexes [LRMCl]. The most surprising result came from the reaction of LPhH with [Ni(COD)2] which gave a Ni(II)-Ph complex bearing a tridentate amidoquinoline-aminophosphine ligand. This rearrangement would result from a proton transfer assisted by the Ni0 when stabilized by a Ph substituent at the P, as suggested by DFT calculations and complementary experiments This Ni-Ph complex formed the corresponding benzoyl complex under a CO atm.
As far as I know, this compound(29046-78-4)Related Products of 29046-78-4 can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles