In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Intermolecular Oxidative Addition of Aryl Halides to Platinum(II) Alkyl Complexes, published in 2019-05-28, which mentions a compound: 141556-42-5, mainly applied to arylimidazolylidene platinum alkyl complex metallacycle preparation reductive elimination reaction; crystal structure arylimidazolylidene platinum alkyl complex metallacycle; mol structure arylimidazolylidene platinum alkyl complex metallacycle, Computed Properties of C21H24N2.
The authors report a well-defined example of intermol. aryl halide oxidative addition (OA) to Pt(II). (IMes)PtMe2(L) and (IMes’)PtMe(L) (L = SMe2, pyridine; IMes = N,N-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene; IMes’ = cyclometalated IMes) undergo intermol. OA of Ph iodide (PhI) at 60°, producing toluene via reductive elimination from a proposed Pt(IV) Ph species. Isolation of a model Pt(IV) OA product provides evidence for a Pt(II)/Pt(IV) pathway. The OA of PhI is not limited to Pt(II) IMes complexes; analogous reactions also proceed with phosphine-ligated Pt(II) dialkyl complexes, demonstrating that this reaction is feasible for a variety of electron-rich Pt(II) complexes bearing labile ligands.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles