Gao, Xuebo; Chang, Rong; Rao, Junxin; Hao, Danyang; Zhang, Zhuxia; Zhou, Cong-Ying; Guo, Zhen published the artcile< Halogen-Bonding-Promoted C-H Malonylation of Indoles under Visible-Light Irradiation>, Reference of 4771-48-6, the main research area is indole diethyl bromomalonate photochem malonylation green chem; diethyl indolyl propanedioate preparation.
A halogen-bonding-based electron donor-acceptor (EDA) complex-promoted photoreaction for the synthesis of C2-malonylated indoles was reported. The protocol provided access to a broad range of functionalized indoles in good yields through the coupling reaction of indoles with di-Et bromomalonate under visible-light irradiation without the need for any transition-metal catalyst or photocatalyst.
Journal of Organic Chemistry published new progress about Carboxylic esters Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 4771-48-6 belongs to class indole-building-block, and the molecular formula is C10H9NO, Reference of 4771-48-6.
Referemce:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles