On October 5, 2011, Isaji, Hisaaki; Nakazaki, Atsuo; Isobe, Minoru; Nishikawa, Toshio published an article.Reference of Methyl 2-(6-bromo-1H-indol-3-yl)acetate The title of the article was Concise synthesis of deformylflustrabromine, a marine indole alkaloid, through a 2-propynyl dicobalt hexacarbonyl complex. And the article contained the following:
Deformylflustrabromine, a marine indole alkaloid, was synthesized from 6-bromotryptamine, a plausible biosynthetic precursor, without protection of the amino group by a two-step reverse prenylation involving the Nicholas reaction and reductive decomplexation of the resulting acetylene dicobalt hexacarbonyl complex. The experimental process involved the reaction of Methyl 2-(6-bromo-1H-indol-3-yl)acetate(cas: 152213-63-3).Reference of Methyl 2-(6-bromo-1H-indol-3-yl)acetate
The Article related to deformylflustrabromine synthesis, Alkaloids: Alkaloids Containing One Nitrogen Atom In A Ring and other aspects.Reference of Methyl 2-(6-bromo-1H-indol-3-yl)acetate
Referemce:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles