Zhang, Hailong published the artcileConstruction of the N1-C3 Linkage Stereogenic Centers by Catalytic Asymmetric Amination Reaction of 3-Bromooxindoles with Indolines, Product Details of C8H8ClN, the main research area is nickel catalyst asym amination bromooxindole indoline.
The catalytic asym. amination reaction of 3-bromooxindoles with indolines for the construction of the N1-C3 linkage stereogenic centers has been realized for the first time. E.g., in presence of Ni(OAc)2, ligand (I), and DABCO in MTBE, amination of 3-bromooxindole derivative (II) with indoline gave 87% III. Moreover, the racemic substrates (3-substituted indolines) were also applicable under the same chiral conditions. The newly developed method conveniently led to a formal synthesis of (+)-psychotrimine.
Organic Letters published new progress about Amination catalysts. 41910-64-9 belongs to class indole-building-block, name is 4-Chloroindoline, and the molecular formula is C8H8ClN, Product Details of C8H8ClN.
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Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles