Chemistry, like all the natural sciences, begins with the direct observation of nature— in this case, of matter.50-99-7, Name is Dextrose, SMILES is O=C[C@@H]([C@H]([C@@H]([C@@H](CO)O)O)O)O, belongs to indole-building-block compound. In a document, author is Yuan, Chang, introduce the new discover, Computed Properties of C6H12O6.
Phosphine-Catalyzed [3+2] Cycloaddition and Vinylation of Indole-Derived alpha,alpha-Dicyanoolefins with gamma-Substituted Allenoates
A phosphine-catalyzed [3+2] cycloaddition of gamma-substituted allenoates with alpha,alpha-dicyanoolefins has been established, affording indole-incorporated highly functionalized cyclopentenes. In addition, the vinylation of indole-derived alpha,alpha-dicyanoolefins has also been realized under the same reaction conditions by switching to indole-derived alpha,alpha-dicyanoolefins without protective group at N-1 position.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 50-99-7 is helpful to your research. Computed Properties of C6H12O6.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles