Final Thoughts on Chemistry for Ethyl indole-2-carboxylate

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The Diels-Alder reaction of quinones and (E)-3-arylpropenal N,N-dimethylhydrazones only proceeds with 1,4-naphthoquinone as the dienophile.The addition of Lewis acids leads to the formation of trans-2,3-dihydrobenzofurans in a highly regioselective <3+2> process.When propenal N,N-dimethylhydrazones 4 and 5 were allowed to react with 1,4-benzoquinone and boron trifluoride, an unprecedented oxidative rearrangement took place yielding indole-3-carboxaldehyde N,N-dimethylhydrazones 7 and 8, respectively.

Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.HPLC of Formula: C11H11NO2, you can also check out more blogs about3770-50-1

Reference：
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles