An article Lewis Acid-Activated Reactions of Silyl Ketenes for the Preparation of alpha-Silyl Carbonyl Compounds WOS:000497259900009 published article about CATIONIC-POLYMERIZATION; EFFICIENT SYNTHESIS; CHEMISTRY; SILYLKETENES; POLYMERS in [Mitchell, Sarah M.; Xiang, Yuanhui; Matthews, Rachael; Arnburgey, Alexis M.] Case Western Reserve Univ, Dept Chem, 10900 Euclid Ave, Cleveland, OH 44106 USA; [Pentzer, Emily B.] Texas A&M Univ, Dept Mat Sci & Engn, 3003 TAMU, College Stn, TX 77843 USA; [Pentzer, Emily B.] Texas A&M Univ, Dept Chem, 3003 TAMU, College Stn, TX 77843 USA in 2019, Cited 29. The Name is 3-(Trifluoromethyl)phenol. Through research, I have a further understanding and discovery of 98-17-9. Product Details of 98-17-9
Silyl-substituted ketenes are attractive molecular building blocks due to their stability and ease of storage, as opposed to unstable alkyl and aryl ketenes. To better understand the reactivity of silyl ketenes and, in turn, their use in the preparation of highly functionalized small molecules, the reaction of silyl ketenes with different nucleophiles was studied. The addition of alcohol, amine, or thiol nucleophiles to the central carbon of silyl ketene, followed by proton transfer afforded alpha-silyl ester, amide, or thio-ester, respectively. Catalytic amounts of Lewis acid greatly increase the rate of the reaction, and the impact of nucleophile, Lewis acid, and silyl substituent are evaluated. The small molecules produced from these reactions give insight into the use of silyl ketenes as building blocks for complex molecular structures.
About 3-(Trifluoromethyl)phenol, If you have any questions, you can contact Mitchell, SM; Xiang, Y; Matthews, R; Arnburgey, AM; Pentzer, EB or concate me.. Product Details of 98-17-9
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Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles