Safety of Benzyl Alcohol. In 2020.0 SUSTAIN ENERG FUELS published article about METAL-ORGANIC FRAMEWORK; GAMMA-VALEROLACTONE; HIGHLY EFFICIENT; FURFURYL ALCOHOL; ZRO2 NANOPARTICLES; LEVULINIC ACID; BIOMASS; CONVERSION; LEWIS; DERIVATIVES in [He, Jian] Jishou Univ, Key Lab Hunan Forest Prod & Chem Ind Engn, Zhangjiajie 427000, Peoples R China; [He, Jian; Xu, Yufei; Yu, Zhaozhuo; Li, Hu; Zhao, Wenfeng; Wu, Hongguo; Yang, Song] Guizhou Univ, State Key Lab Breeding Base Green Pesticide & Agr, Ctr Res & Dev Fine Chem,State Local Joint Lab Com, Minist Educ,Key Lab Green Pesticide & Agr Bioengn, Guiyang 550025, Guizhou, Peoples R China in 2020.0, Cited 59.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
The effective and economically feasible tandem synthesis of gamma-valerolactone (GVL), a renowned bio-based platform molecule with great promising applications in the production of drop-in chemicals, liquid fuels and polymers, is significantly vital and challenging. Herein, we for the first time describe a direct and effective catalytic system based on ZrOCl2 center dot 8H(2)O capable of facilitating the one-pot one-step tandem synthesis of GVL from bio-based furfural or furfuryl alcohol in 2-propanol by integrating sequential transfer hydrogenation, ring-opening, and transfer hydrogenation-cyclization reactions. A maximum GVL yield of 63.3% and 52.1% was achieved from furfuryl alcohol and furfural at 200 degrees C, respectively. The synergistic effect of [ZrO(OH)(2)](n)center dot xH(2)O species and Bronsted acid species H+, derived from in situ hydrolysis of ZrOCl2 center dot 8H(2)O, is accountable for its remarkable catalytic performance. Moreover, calcination of the leftover solid after tandem synthesis of GVL could fabricate a hollow microrod ZrO2 material, in which the formation of a microrod morphology and hollow structure was probably attributed to the electrostatic repulsion forces among particles in the alcohol solution and removal of generated humins/coke during the reactions within collected solids via calcination, respectively. Importantly, hollow microrod ZrO2 innovatively featuring a high BET surface area, a large amount of acid-base sites and facile active-site accessibility thereby exhibited a superior performance in the catalytic transfer hydrogenation of biomass-derived aldehydes or ketones to ZrO2 prepared by the precipitation method.
About Benzyl Alcohol, If you have any questions, you can contact He, J; Xu, YF; Yu, ZZ; Li, H; Zhao, WF; Wu, HG; Yang, S or concate me.. Safety of Benzyl Alcohol
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles