Authors Trost, BM; Zuo, ZJ; Schultz, JE; Anugula, N; Carr, KA in ROYAL SOC CHEMISTRY published article about DICYCLOHEXYLCHLOROBORANE TRIETHYLAMINE; ENANTIOSELECTIVE CONSTRUCTION; REGIOSPECIFIC SYNTHESIS; ASYMMETRIC ALLYLATION; CONVENIENT REAGENT; ALPHA-ALLYLATION; ALDOL REACTIONS; BORON; KETONES; STEREOCENTERS in [Trost, Barry M.; Zuo, Zhijun; Schultz, Johnathan E.; Anugula, Nagaraju; Carr, Katherine A.] Stanford Univ, Dept Chem, Stanford, CA 94305 USA in 2020, Cited 50. Recommanded Product: 80-59-1. The Name is (E)-2-Methylbut-2-enoic acid. Through research, I have a further understanding and discovery of 80-59-1
The development of the palladium-catalyzed allylic alkylation of in situ generated boron enolates via tandem 1,4-hydroboration is reported. Investigation of the reaction revealed insights into specific catalyst electronic features as well as a profound leaving group effect that proved crucial for achieving efficient allylic alkylation of ester enolates at room temperature and ultimately a highly preparatively useful synthesis of notoriously challenging acyclic all-carbon quaternary stereocenters. The method demonstrates boron enolates as viable pro-nucleophiles in transition-metal catalyzed allylic alkylation, potentially opening up further transformations outside their traditional use.
About (E)-2-Methylbut-2-enoic acid, If you have any questions, you can contact Trost, BM; Zuo, ZJ; Schultz, JE; Anugula, N; Carr, KA or concate me.. Recommanded Product: 80-59-1
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles