Authors Ould, DMC; Tran, TTP; Rawson, JM; Melen, RL in ROYAL SOC CHEMISTRY published article about HYDROBORATION; PHOSPHORUS; SULFUR; CRYSTAL; AMIDES; CATION; BOND in [Ould, Darren M. C.; Melen, Rebecca L.] Cardiff Univ, Sch Chem, Cardiff Catalysis Inst, Main Bldg, Cardiff CF10 3AT, S Glam, Wales; [Tran, Thao T. P.; Rawson, Jeremy M.] Univ Windsor, Dept Chem & Biochem, 401 Sunset Ave, Windsor, ON, Canada in 2019.0, Cited 48.0. COA of Formula: C7H8O. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6
The reaction of either toluene-3,4-dithiol or benzene dithiol with phosphorus(iii) trihalides generates the corresponding benzo-fused 1,3,2-dithiaphospholes, RC6H3S2PX (R = Me (1), R = H (2); X = Cl, Br, I). The P-chloro-dithiaphospholes undergo: (a) halogen abstraction reactions with Lewis acids forming phosphenium cations; (b) substitution with LiHMDS base and; (c) reduction chemistry with sodium metal to generate the P-P sigma-bonded dimer, (RC6H3S2P)(2). Reduction catalysis of aldehydes with pinacolborane using dithiaphospholes is compared with their dioxaphosphole and diazaphosphole counterparts as pre-catalysts, revealing interesting differences in the reactivity of this series of compounds.
COA of Formula: C7H8O. About Benzyl Alcohol, If you have any questions, you can contact Ould, DMC; Tran, TTP; Rawson, JM; Melen, RL or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles