SDS of cas: 98-17-9. Recently I am researching about VERLEY-TYPE REDUCTION; ALCOHOLIC SUSPENSIONS; ROOM-TEMPERATURE; AQUEOUS-PHASE; CHEMOSELECTIVE REDUCTION; PHOTOINDUCED REDUCTION; DIOXIDE; NITROBENZENE; NANOPARTICLES; ALKENES, Saw an article supported by the JSPS KAKENHIMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of ScienceGrants-in-Aid for Scientific Research (KAKENHI) [17H03462, 17H04967]; Precursory Research for Embryonic Science and Technology (PRESTO); Japan Science and Technology Agency (JST)Japan Science & Technology Agency (JST); MEXT-Supported Program for the Strategic Research Foundation at Private UniversitiesMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT); MEXT and Kindai University; Japan Society for the Promotion of Science (JSPS)Ministry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of Science [15J11412]; Faculty of Science and Engineering, Kindai University. Published in ELSEVIER in AMSTERDAM ,Authors: Kinoshita, A; Nakanishi, K; Yagi, R; Tanaka, A; Hashimoto, K; Kominami, H. The CAS is 98-17-9. Through research, I have a further understanding and discovery of 3-(Trifluoromethyl)phenol
Since photocatalytic reactions are almost consistent with the concept of green chemistry, substance conversion using photocatalysts has recently attracted the attention of researchers in the fields of organic chemistry, physical chemistry and material chemistry. We investigated photoinduced ring hydrogenation of phenol over a metal-loaded titanium(IV) oxide (TiO2) photocatalyst without the use of H-2 gas and we report here the effects of various parameters, including the type and amount of metal co-catalyst loaded on TiO2 and the kinds of solvents and hole scavengers, on the ring hydrogenation. We found that the combination of an Rh co-catalyst, water and oxalic acid resulted in the highest yield of cyclohexanol. Detailed analyses revealed that phenol was first hydrogenated to cyclohexanone via keto-enol tautomerism of cyclohexenol followed by hydrogenation of cyclohexanone to cyclohexanol and that adsorption of phenol onto Rh-TiO2 is a factor of great importance for the ring hydrogenation.
About 3-(Trifluoromethyl)phenol, If you have any questions, you can contact Kinoshita, A; Nakanishi, K; Yagi, R; Tanaka, A; Hashimoto, K; Kominami, H or concate me.. SDS of cas: 98-17-9
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles