Name: Benzyl Alcohol. In 2019.0 INORG CHEM published article about GAUSSIAN-BASIS SETS; MOLECULAR CALCULATIONS; ELECTRONIC-STRUCTURE; DFT CALCULATIONS; IRON; AMINES; PSEUDOPOTENTIALS; ALCOHOLS; BEARING; APPROXIMATION in [Pecak, Jan; Mastalir, Matthias; Linert, Wolfgang; Kirchner, Karl] Vienna Univ Technol, Inst Appl Synthet Chem, Getreidemarkt 9, A-1060 Vienna, Austria; [Stoeger, Berthold] Vienna Univ Technol, Xray Ctr, Getreidemarkt 9, A-1060 Vienna, Austria; [Veiros, Luis F.] Univ Lisbon, Inst Super Tecn, Ctr Quim Estrutural, Ave Rovisco Pais 1, P-1049001 Lisbon, Portugal; [Ferreira, Liliana P.] Univ Lisbon, Fac Ciencias, Biosyst & Integrat Sci Inst, P-1749016 Lisbon, Portugal; [Ferreira, Liliana P.] Univ Coimbra, Dept Phys, P-3004516 Coimbra, Portugal; [Pignitter, Marc] Univ Vienna, Dept Physiol Chem, Fac Chem, Althanstr 14, A-1090 Vienna, Austria in 2019.0, Cited 58.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
The synthesis and characterization of air-stable cationic mono nitrosonium Fe(I) PNP pincer complexes of the type [Fe(PNP)(NO)Cl](+) are described. These complexes are obtained via direct nitroslyation of [Fe(PNP)Cl-2] with nitric oxide at ambient pressure. On the basis of magnetic and EPR measurements as well as DFT calculations, these compounds were found to adopt a low-spin d(7) configuration and feature a nearly linear bound NO ligand suggesting (FeNO+)-N-I rather than (FeNO center dot)-N-II character. X-ray structures of all nitrosonium Fe(I) PNP complexes are presented. Preliminary investigations reveal that [Fe(PNPNH-iPr)(NO)(Cl](+) efficiently catalyzes the conversion of primary alcohols and aromatic and benzylic amines to yield mono N-alkylated amines in good isolated yields.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles