Wang, W; Song, JR; Li, ZY; Zhong, T; Chi, Q; Ren, H; Pan, WD in [Wang, Wei; Li, Zhi-Yao; Pan, Wei-Dong] Guizhou Univ, Sch Pharmaceut Sci, Huaxi Ave South, Guiyang 550025, Peoples R China; [Song, Jun-Rong; Zhong, Ting; Chi, Qin; Ren, Hai; Pan, Wei-Dong] Guizhou Med Univ, Key Lab Chem Nat Prod Guizhou Prov, State Key Lab Funct & Applicat Med Plants, Guiyang 550014, Peoples R China; [Song, Jun-Rong; Zhong, Ting; Chi, Qin; Ren, Hai; Pan, Wei-Dong] Chinese Acad Sci, Guiyang 550014, Peoples R China published Copper-catalyzed aerobic oxidative radical alkoxycyclization of tryptamines to access 3-alkoxypyrroloindolines in 2021.0, Cited 39.0. Recommanded Product: Benzyl Alcohol. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
We report a copper-catalyzed alkoxycyclization of tryptamine derivatives with O-2 as the sole oxidant, leading to a variety of C3a-alkoxypyrroloindolines in good yields with high diastereoselectivities. This reaction involves an interesting double catalytic cycle in which copper-catalyzed carboamination cyclization is favored to form the C-3 radical pyrrolidinoindoline intermediate, then a copper-catalytic radical alkoxylation reaction proceeds smoothly.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles