Recently I am researching about HOMOPROPARGYLIC ALCOHOLS; ENOL-ETHERS; CYCLOISOMERIZATION; HYDROAMINATION; BOND; HYDROALKOXYLATION; CYCLIZATION; INDOLES; ACETALS; ROUTE, Saw an article supported by the National Institutes of Health (NIGMS)United States Department of Health & Human ServicesNational Institutes of Health (NIH) – USANIH National Institute of General Medical Sciences (NIGMS) [R01GM110560]; NIHUnited States Department of Health & Human ServicesNational Institutes of Health (NIH) – USA [S10RR028859]; NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCESUnited States Department of Health & Human ServicesNational Institutes of Health (NIH) – USANIH National Institute of General Medical Sciences (NIGMS) [R01GM110560] Funding Source: NIH RePORTER. Quality Control of m-Methoxyphenol. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Costello, JP; Ferreira, EM. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol
The steric and electronic drivers of regioselectivity in platinum -catalyzed intramolecular hydroalkoxylation are elucidated. A branch point is found that divides the process between 5-exo and 6-endo selective processes, and enol ethers can be accessed in good yields for both oxygen heterocycles. The main influence arises from an electronic effect, where the alkyne substituent induces a polarization of the alkyne that leads to preferential heteroatom attack at the more electron -deficient carbon. The electronic effects are studied in other contexts, including hydroacyloxylation and hydroamination, and similar trends in directionality are predominant although not uniformly observed.
Quality Control of m-Methoxyphenol. Welcome to talk about 150-19-6, If you have any questions, you can contact Costello, JP; Ferreira, EM or send Email.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles