An article Rhodium-catalyzed carbonylative coupling of alkyl halides with thiols: a radical process faster than easier nucleophilic substitution WOS:000618040500007 published article about ALLYLIC ALCOHOLS; CARBON-MONOXIDE; PALLADIUM; THIOCARBONYLATION; COMPLEXES; THIOESTERS; ACTIVATION; BROMIDES; LIGANDS; ESTERS in [Ai, Han-Jun; Rabeah, Jabor; Brueckner, Angelika; Wu, Xiao-Feng] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany; [Wu, Xiao-Feng] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China in 2021.0, Cited 44.0. Category: indole-building-block. The Name is Mequinol. Through research, I have a further understanding and discovery of 150-76-5
How to make a carbonylative coupling faster than the easier nucleophilic substitution? In this communication, a rhodium-catalyzed radical-based carbonylative coupling of alkyl halides with thiolphenols has been realized. Thioesters were isolated in good yields in general.
About Mequinol, If you have any questions, you can contact Ai, HJ; Rabeah, J; Bruckner, A; Wu, XF or concate me.. Category: indole-building-block
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles