Product Details of 100-51-6. Yamashita, M; Kawasumi, Y; Tachibana, Y; Horiuchi, S; Yamamoto, K; Murahashi, T in [Yamashita, Mitsuki; Kawasumi, Yuna; Yamamoto, Koji; Murahashi, Tetsuro] Tokyo Inst Technol, Dept Chem Sci & Engn, Meguro Ku, Tokyo 1528552, Japan; [Tachibana, Yuki; Horiuchi, Shinnosuke] Natl Inst Nat Sci, Inst Mol Sci, Res Ctr Integrat Mol Syst CIMoS, Okazaki, Aichi 4448787, Japan; [Tachibana, Yuki] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan published Extended Open-Chain Polyenides as Versatile Delocalized Anion Ligands for Metal Chain Clusters in 2019, Cited 75. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
Although small cyclic- and open-chain unsaturated hydrocarbon anions such as cyclopentadienide and open-chain pentadienide are used as the strongly electron-donating auxiliary ligands for metal complexes, more extended pi-conjugated unsaturated hydrocarbon anions have rarely been used in coordination chemistry, despite their potential ability to serve as the multiply bridging pi-ligands for metal clusters. This work reports isolation of metal chain clusters bearing the multi-dentate, open-chain extended unsaturated hydrocarbon anion ligands. The extended open-chain pi-conjugated polyenyl ligands could effectively stabilize oxidized palladium chains, including an unprecedented [Pd-4](4+) chain.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles