An article Acceptorless dehydrogenative construction of C?N and C?C bonds through catalytic aza-Wittig and Wittig reactions in the presence of an air-stable ruthenium pincer complex WOS:000472451000021 published article about N-HETEROCYCLIC CARBENES; DITHIA-CONTAINING LIGANDS; METHANOL DEHYDROGENATION; EFFICIENT HYDROGENATION; BORROWING HYDROGEN; SECONDARY ALCOHOLS; ALPHA-ALKYLATION; ORGANIC AZIDES; PRIMARY AMINES; OXIDANT-FREE in [Biswas, Nandita; Das, Kalicharan; Sardar, Bitan; Srimani, Dipankar] Indian Inst Technol Guwahati, Dept Chem, Gauhati 781039, Assam, India in 2019.0, Cited 99.0. Recommanded Product: 100-51-6. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6
The construction of C?N bonds was achieved by the dehydrogenative coupling of alcohol and azide via aza-Wittig type reaction. The reaction is catalyzed by an acridine-derived ruthenium pincer complex and does not use any oxidant. The present protocol offers a wide substrate scope, including aliphatic, aryl or heteroaryl alcohol/azides. This expeditious protocol was successfully applied to construct a C?C bond directly from alcohol via dehydrogenative Wittig reaction. Furthermore, the synthesis of structurally important pyrrolo[1,4]benzodiazepine derivatives was also achieved by this methodology.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles