COA of Formula: C7H8O. Recently I am researching about SELECTIVE HYDROGENATION; SUPPORTED PLATINUM; NICKEL PHOSPHIDE; BIMETALLIC CATALYSTS; PHENOLIC-COMPOUNDS; HYDRODEOXYGENATION; CARBON; PYRIDINE; ADSORPTION; IR, Saw an article supported by the NSF CAREER AwardNational Science Foundation (NSF)NSF – Office of the Director (OD) [CBET-1351609]; Defense University Research Instrumentation Program under AFOSR [FA9550-17-1-0376]; Bayer Center of Environmental Science & Technology (CEST) Fellowship; Patrick and Jana Eilers Fellowship through ND Energy. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Bonita, Y; O’Connell, TP; Miller, HE; Hicks, JC. The CAS is 100-51-6. Through research, I have a further understanding and discovery of Benzyl Alcohol
Bimetallic transition metal phosphide catalysts are promising materials for low-temperature, liquid-phase hydrogenation reactions. This work explores the chemoselective hydrogenation ability of RuMoP using various functionalized aromatic hydrocarbons to provide insight into how the functional groups compete for reduction on the surface of RuMoP. Using molecular hydrogen as the reductant, high selectivity (similar to 99%) to reduction of the substituent is achieved for the hydrogenation of electron withdrawing functionalities such as nitrobenzene, benzaldehyde, and benzophenone with RuMoP to yield aniline, benzyl alcohol, and diphenylmethanol, respectively. In contrast, aromatics with electron donating groups such as phenol, anisole, and toluene, show high ring hydrogenation selectivity (similar to 99%) to form cyclohexanol, methoxycyclohexane, and methyl cyclohexane, respectively, although the reaction proceeded slowly with RuMoP. Pyridine adsorption was studied via diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), which provided evidence of surface electron deficient sites (i.e., Lewis acids) that are responsible for targeting the electron-rich portion of the substrate. Additional DRIFTS experiments were performed using nitrobenzene, anisole, and a mixture of the two. From these experiments, features associated with -NO2 adsorption in nitrobenzene and ring adsorption in anisole were observed, which correlated well with the observed reaction results. Finally, a solvent study provided evidence for the competitive adsorption of isopropanol and the pi-electrons from the aromatic ring of phenol with the former being more favorable on RuMoP surface.
COA of Formula: C7H8O. Bye, fridends, I hope you can learn more about C7H8O, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles