Thangapriya, C; Ilaamirthamani, S; Kumarraja, M in [Thangapriya, Cheirmakani] Sri Kaliswari Coll Autonomous, Dept Chem, Sivakasi, India; [Ilaamirthamani, Simsonrubarathinam; Kumarraja, Mayilvasagam] Ayya Nadar Janaki Ammal Coll Autonomous, Ctr Res & Postgrad Studies Chem, Sivakasi 626124, Tamil Nadu, India published Highly regioselective O-allylation of phenol derivatives using MMZ(Cu(I)Y) catalyst in 2020.0, Cited 26.0. Quality Control of 4′-Hydroxyacetophenone. The Name is 4′-Hydroxyacetophenone. Through research, I have a further understanding and discovery of 99-93-4.
A clean and effective method has been developed for the regioselective of O-allylation of phenol derivatives using a recyclable Cu(I)-exchanged multi-size porous material. Ease of preparation of catalyst through simple solid-state exchange and its compatibility in producing excellent amount of O-allylated products and a plausible mechanistic pathway for the regioselectivity are highlighted. This reported procedure is not requiring any external stabilizing ligand for Cu(I) species and further purification of products.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles