I found the field of Chemistry very interesting. Saw the article Dual Nickel/Ruthenium Strategy for Photoinduced Decarboxylative Cross-Coupling of alpha,beta-Unsaturated Carboxylic Acids with Cycloketone Oxime Esters published in 2021. Application In Synthesis of 4-Methoxybenzaldehyde, Reprint Addresses Lu, XY (corresponding author), ChuZhou Univ, Sch Mat & Chem Engn, Chuzhou 239000, Peoples R China.; Lu, XY (corresponding author), AnHui Univ, Sch Chem & Chem Engn, Hefei 230601, Peoples R China.. The CAS is 123-11-5. Through research, I have a further understanding and discovery of 4-Methoxybenzaldehyde
Herein, a dual nickel/ruthenium strategy is developed for photoinduced decarboxylative cross-coupling between alpha,beta-unsaturated carboxylic acids and cycloketone oxime esters. The reaction mechanism is distinct from previous photoinduced decarboxylation of alpha,beta-unsaturated carboxylic acids. This reaction might proceed through a nickelacyclopropane intermediate. The C(sp(2))-C(sp(3)) bond constructed by the aforementioned reaction provides an efficient approach to obtaining various cyanoalkyl alkenes, which are synthetically valuable organic skeletons in organic and medicinal chemistry, under mild reaction conditions. The protocol tolerates many critical functional groups and provides a route for the modification of complex organic molecules.
Application In Synthesis of 4-Methoxybenzaldehyde. About 4-Methoxybenzaldehyde, If you have any questions, you can contact Lu, XY; Xia, ZJ; Gao, A; Liu, QL; Jiang, RC; Liu, CC or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles