In 2020.0 J ORGANOMET CHEM published article about N-ALKYLATION; ALCOHOLS; AMINES; WATER; OXYGENATION; REDUCTION; CHEMISTRY; COPPER in [Li, Ming; Hsu, Yen-Pin; Liu, Yi-Hung; Peng, Shie-Ming; Liu, Shiuh-Tzung] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan in 2020.0, Cited 42.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6. Formula: C7H8O
Complexation of 1,8-naphthyridine(Np)-2-carboxylic derivatives L-1-L-3 [L-1 = Np-2-COOH, L-2 = Np-2-CONH2, L-3 = Np-2-CONHCH2Py] with [Ir(COD)(mu-OMe)](2) yielded the corresponding complexes [Ir(COD)(L-n)] (1 similar to 3, n = 1 similar to 3, respectively). The potential tridentate L-3 behaves as a bidentate donor in the complex 3. Treatment of L-1 with [Ir(COD)Cl](2) under nitrogen atmosphere gave a Ir(III) hydride complex [Ir(COD)(L-1)HCl] (4). However, carrying out the reaction in the presence of oxygen rendered a Ir(III) dichloride species [Ir(COD)(L-1)Cl-2] (5). All these complexes were characterized by spectroscopic analyses and X-ray single crystal determination. Catalytic activity of iridium complexes in amination of amines with alcohols was screened. It appears that iridium amido complexes 2 and 3 show excellent catalytic activity on amination of anilines with alcohols in the presence of Cs2CO3 at 120 degrees C. (c) 2020 Published by Elsevier B.V.
Formula: C7H8O. About Benzyl Alcohol, If you have any questions, you can contact Li, M; Hsu, YP; Liu, YH; Peng, SM; Liu, ST or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles