Lee, J; Lee, J; Jung, HM; Kim, D; Park, J; Chang, S in [Lee, Jia; Lee, Jeonghyo; Jung, Hoimin; Kim, Dongwook; Park, Juhyeon; Chang, Sukbok] Inst Basic Sci IBS, Ctr Catalyt Hydrocarbon Functionalizat, Daejeon 34141, South Korea; [Lee, Jia; Lee, Jeonghyo; Jung, Hoimin; Kim, Dongwook; Park, Juhyeon; Chang, Sukbok] Korea Adv Inst Sci & Technol KAIST, Dept Chem, Daejeon 34141, South Korea published Versatile Cp*Co(III)(LX) Catalyst System for Selective Intramolecular C-H Amidation Reactions in 2020, Cited 62. Formula: C7H8O2. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6.
Herein, we report the development of a tailored cobalt catalyst system of Cp*Co(III)(LX) toward intramolecular C-H nitrene insertion of azidoformates to afford cyclic carbamates. The cobalt complexes were easy to prepare and bench-stable, thus offering a convenient reaction protocol. The catalytic reactivity was significantly improved by the electronic tuning of the bidentate LX ligands, and the observed regioselectivity was rationalized by the conformational analysis and DFT calculations of the transition states. The superior performance of the newly developed cobalt catalyst system could be broadly applied to both C(sp(2))-H and C(sp(3))-H carbamation reactions under mild conditions.
About m-Methoxyphenol, If you have any questions, you can contact Lee, J; Lee, J; Jung, HM; Kim, D; Park, J; Chang, S or concate me.. Formula: C7H8O2
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles