The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Nickel(II) chloride ethylene glycol dimethyl ether complex(SMILESS: COCCOC.Cl[Ni]Cl,cas:29046-78-4) is researched.Recommanded Product: 1,4,7,10,13-Pentaoxa-16-azacyclooctadecane. The article 《Synthesis, structures and reactivity of bis(iminophosphorano)methanide chelate complexes with transition metal of cobalt, nickel, palladium and iridium》 in relation to this compound, is published in Polyhedron. Let’s take a look at the latest research on this compound (cas:29046-78-4).
The organolithium bis(iminophosphorano)methandiide dimer [Li2C(Ph2P:NSiMe3)2]2 ([Li2-L]2, L = {C(Ph2P:NSiMe3)2}) reacts with 2 equiv of [Co(PPh3)3Cl], [Ni(dme)Br2], [Ni(dme)Cl2] in situ, instead of forming nitrogen chelate carbene metal complexes, it generates novel monomeric and bimetallic bis(iminophosphorano)methanide complexes of [ClCo{CH(Ph2P:NSiMe3)2}]2 (1), [BrNi{CH(Ph2P:NSiMe3)2}]2 (2), [ClNi{CH(Ph2P:NSiMe3)2}]2 (3). While organolithium bis(iminophosphorano)methanide ([HLiL], L = {C(Ph2P:NSiMe3)2}) reacted with 0.5 equiv of [Pd(allyl)Cl]2 and 1 equiv of [Pd(cod)Cl2] synthesized new bis(iminophosphorano)methanide palladium complexes of [Pd(allyl){CH(Ph2P:NSiMe3)2}] (4) and [PdCl{CH(Ph2P:NSiMe3)2}]2 (5) in situ. One iridium complex, with one substitute Ph C-H bond activation, [Ir(cod){CH(Ph(C6H4)P:NSiMe3)2}Li(THF)] (6) was generated by reaction of 1:1 ratio [Li2L]2 and [Ir(cod)Cl]2 in THF. All the synthesized complexes (1-6) were isolated in solid and were structurally characterized by X-ray diffraction.
Compound(29046-78-4)COA of Formula: C4H10Cl2NiO2 received a lot of attention, and I have introduced some compounds in other articles, similar to this compound(Nickel(II) chloride ethylene glycol dimethyl ether complex), if you are interested, you can check out my other related articles.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles