Recently I am researching about ASYMMETRIC HENRY REACTION; C-H AMINATION; STEREOCONTROLLED SYNTHESIS; INTERMOLECULAR REACTIONS; BOND FORMATION; ALCOHOLS; ETHERS; PSEUDOEPHEDRINE; CARBOCATIONS; 1,2-DIAMINES, Saw an article supported by the NSERCNatural Sciences and Engineering Research Council of Canada (NSERC); NSERC/Servier Senior Industrial Research Chair initiative. Recommanded Product: m-Methoxyphenol. Published in CANADIAN SCIENCE PUBLISHING in OTTAWA ,Authors: Hensienne, R; Cusson, JP; Chenard, E; Hanessian, S. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol
A series of alkyl and alkenyl p-methoxy arenes containing alpha,beta-disubstituted diamino and amino alcohol groups were synthesized from beta-nitro and beta-azido benzylic alcohols in the presence of AuCl3 as catalyst. The formation of predominantly syn-disubstituted products were rationalized on the basis of mechanistic considerations and transition state models relying on A(1,3)-allylic strain. The products could have utility in the design of medicinally relevant compounds and as chiral ligands for asymmetric catalysis. A new synthesis of (+)-sertraline (Zoloft) was achieved.
Recommanded Product: m-Methoxyphenol. About m-Methoxyphenol, If you have any questions, you can contact Hensienne, R; Cusson, JP; Chenard, E; Hanessian, S or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles