An article A Novel Approach Based on Two-Dimensional Correlation Spectroscopy to Determine the Stoichiometric Ratio of Two Substances Involved in Intermolecular Interactions WOS:000479650000001 published article about ANION-PI INTERACTIONS; SAMPLE DESIGN SCHEME; FT-IR; COMPLEXES; CRYSTAL; TRANSFORMATION; DERIVATIVES; SPECTRA; ACID in [Li, Xiaopei; Ozaki, Yukihiro] Dalian Polytech Univ, Instrumental Anal Ctr, Dalian, Peoples R China; [Li, Xiaopei; Zeng, Yiwei; Xu, Yizhuang; Noda, Isao; Wu, Jinguang] Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Beijing, Peoples R China; [Deng, Gang] Dalian Polytech Univ, Coll Biol Engn, Dalian, Peoples R China; [Ozaki, Yukihiro] Kwansei Gakuin Univ, Sch Sci & Technol, Dept Chem, Sanda, Hyogo, Japan; [Noda, Isao] Univ Delaware, Dept Mat Sci & Engn, Newark, DE USA in 2019.0, Cited 45.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6. Safety of Benzyl Alcohol
A novel technique called AOSD@Job’s, combining asynchronous orthogonal sample design scheme (AOSD) with Job’s method, is proposed to estimate the stoichiometric ratio of two substances that form a supramolecular aggregate under intermolecular interactions. First, a mathematical analysis was performed along with the procedure of the AOSD@Job’s method. Then, the validity of the AOSD@Job’s method was manifested by computer simulation on two model systems. Finally, the AOSD@Job’s method was applied on two real chemical systems. The stoichiometric ratio between the coordination complex of Ni2+ and ethylenediaminetetraacetic acid disodium salt (EDTA) was estimated to be 1.0. Benzyl alcohol (BA) and beta-cyclodextrin (beta-CD) were determined to form a 1 : 1 host-guest complex. These values were consistent with the values reported in the literature. Compared with the traditional Job’s method, the AOSD@Job’s method has an evident advantage since it is still valid even if all the peaks of the supramolecular aggregate severely overlap with the peaks of the substances that form the aggregate.
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,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles