Authors Yamaguchi, M; Hagiwara, R; Gayama, K; Suzuki, K; Sato, Y; Konishi, H; Manabe, K in AMER CHEMICAL SOC published article about C-H ARYLATION; PHOSPHINE-LIGANDS; METAL; AMINATION; INHIBITORS; NUCLEUS; FUNCTIONALIZATION; DEAROMATIZATION; DERIVATIVES; CYCLIZATION in [Yamaguchi, Miyuki; Hagiwara, Ryoya; Gayama, Kanami; Suzuki, Kohei; Sato, Yusuke; Konishi, Hideyuki; Manabe, Kei] Univ Shizuoka, Sch Pharmaceut Sci, Shizuoka 4228526, Japan in 2020, Cited 87. Recommanded Product: 3-(Trifluoromethyl)phenol. The Name is 3-(Trifluoromethyl)phenol. Through research, I have a further understanding and discovery of 98-17-9
A palladium-dihydroxyterphenylphosphine (DHTP) catalyst was successfully applied to the direct C3-arylation of N-unsubstituted indoles with aryl chlorides, triflates, and nonaflates. This catalyst showed C3-selectivity, whereas catalysts with other structurally related ligands exhibited N1-selectivity. Complex formation between the lithium salts of the ligand and the indole is assumed to accelerate the arylation at the C3 position. Reactions using 3-alkylindoles afforded 3,3-disubstituted indolenines, which can be further converted to the corresponding indoline derivatives.
About 3-(Trifluoromethyl)phenol, If you have any questions, you can contact Yamaguchi, M; Hagiwara, R; Gayama, K; Suzuki, K; Sato, Y; Konishi, H; Manabe, K or concate me.. Recommanded Product: 3-(Trifluoromethyl)phenol
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles