In an article, author is Park, Hyowon, once mentioned the application of 21679-14-1, Computed Properties of https://www.ambeed.com/products/21679-14-1.html, Name is 9-β-D-Arabinofuranosyl-2-fluoro-9H-purin-6-amine, molecular formula is C10H12FN5O4, molecular weight is 285.2318, MDL number is MFCD00132942, category is indole-building-block. Now introduce a scientific discovery about this category.
The selective multifunctionalization of indoles by using thiosulfonates, trimethyl sulfoxonium iodide (Me3SOI), and H2O2 was studied. The reaction of thiosulfonates with Me3SOI and H2O2 produced sulfonyl radicals and an iodination reagent, both of which were incorporated in indoles to form 3-iodo-2-sulfonyl indoles under carefully controlled conditions. The related reaction mechanism and the substrate scope of 3-iodo-2-sulfonyl indoles are presented.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles