Archives for Chemistry Experiments of 6-Bromo-5-methyl-1H-indole

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Synthetic Route of 248602-16-6, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.248602-16-6, Name is 6-Bromo-5-methyl-1H-indole, molecular formula is C9H8BrN. In a Article£¬once mentioned of 248602-16-6

Cp?Rh(III)-Catalyzed C-H Bond Difluorovinylation of Indoles with alpha,alpha-Difluorovinyl Tosylate

Unprecedented Rh(III)-catalyzed C-H bond difluorovinylation of indoles has been successfully developed, and this method provided an example of direct difluorovinylation reaction through C-H bond activation which was rarely reported. In this context, N-ethoxycarbamoyl served as the directing group and 2,2-difluorovinyl tosylates were used for the construction of difluorovinyl-substituted indoles. This method provided a practical strategy for difluorovinylation of indoles with moderate to good yields and is characterized by the broad synthetic utility, mild conditions, and high efficiency.

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Reference£º
Indole alkaloid derivatives as building blocks of natural products from?Bacillus thuringiensis?and?Bacillus velezensis?and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles