An article Highly selective hydrogenation of aldehydes promoted by a palladium-based catalyst and its application in equilibrium displacement in a one-enzyme procedure using omega-transaminase WOS:000468001500005 published article about ASYMMETRIC-SYNTHESIS; CHEMOSELECTIVE REDUCTION; CHIRAL AMINES; EFFICIENT; NITRILES; AMINATION; KETONES; NANOCATALYST; CASCADE; DONOR in [Ren, Huihui; Long, Peng; Zhao, Yang; Zhang, Kuan; Fan, Peihan; Wang, Bo] Hainan Univ, Minist Educ, Key Lab Adv Mat Trop Isl Resources, 58 Renmin AVE, Haikou 570228, Hainan, Peoples R China; [Wang, Bo] Hainan Univ, State Key Lab Marine Resource Utilizat South Chin, 58 Renmin AVE, Haikou 570228, Hainan, Peoples R China; [Wang, Bo] Hainan Univ, Coll Mat & Chem Engn, Inst Chem Engn, 58 Renmin AVE, Haikou 570228, Hainan, Peoples R China in 2019.0, Cited 48.0. Safety of Benzyl Alcohol. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6
Presented here is a highly efficient procedure for the selective hydrogenation of aldehydes in the presence of ketones and its application in equilibrium displacement in a one-enzyme procedure catalysed by.-transaminase. A palladium-based heterogeneous catalyst was chemically synthesized from K2PdCl4 and 1,1′-binaphthyl-2,2′-ylenediamine and found to be suitable for selective hydrogenation of aldehydes using H2 of 1 atm, with a wide spectrum of aldehydes being efficiently and selectively reduced to the corresponding alcohols with a selectivity of up to 99%. This catalyst and its developed procedure can be successfully applied in pushing the equilibrium to product formation during transamination in a.-transaminase-promoted one-enzyme procedure via hydrogenation of the co-product, and an array of chiral amines was afforded in good to excellent yields of up to 99% with ees of up to > 99%.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles