Application In Synthesis of Benzyl Alcohol. In 2019.0 J NAT PROD published article about CITRYL-L-GLUTAMATE; CELOMIC FLUID; SENSITIVITY in [Griffith, Corey M.] Univ Calif Riverside, Environm Toxicol Grad Program, Riverside, CA 92521 USA; [Feceu, Abigail; Larive, Cynthia K.; Martin, David B. C.] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA in 2019.0, Cited 15.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
Malylglutamate, a newly identified metabolite in earthworms, was synthesized using a traditional peptide coupling approach for assembling the amide from protected malate and glutamate precursors. The proposed structure (1) and a diastereomer were synthesized, but their NMR spectra did not match the natural sample. Further analysis of the natural sample using HMBC spectroscopy suggested an alternative attachment of the malyl moiety, and beta-malylglutamate (2) diastereomers were synthesized, L,L-2 and D,D-2. NMR spectra were an excellent match with the natural sample, and chiral-phase chromatography was employed to identify (-)-beta-L-malyl-L-glutamate (2) as the isomer native to Eisenia fetida.
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Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles