I found the field of Chemistry very interesting. Saw the article Selective Oxidation of Citronellol over Titanosilicate Catalysts published in 2020.0. SDS of cas: 100-51-6, Reprint Addresses Prech, J (corresponding author), Charles Univ Prague, Fac Sci, Dept Phys & Macromol Chem, Albertov 6, Prague 12843 2, Czech Republic.. The CAS is 100-51-6. Through research, I have a further understanding and discovery of Benzyl Alcohol
Citronellol is one of the most widely used fragrances for bouquetting purposes and it is a starting material for synthesis of several other terpenoids. Nevertheless, few data have been reported on citronellol selective oxidation. Accordingly, we report our findings on the selective oxidation of citronellol with hydrogen peroxide using a set of titanosilicate catalysts with different morphologies and textural properties-conventional titanium silicalite 1 (TS-1), mesoporous TS-1, layered TS-1 and silica-titania pillared TS-1 and also studying the effect of the solvent used. Epoxidation of C6=C7 double bond was the main primary reaction in this system and trace signals of C5 allylic oxidation products were observed without formation of citronellal. Due to the presence of post-synthesis introduced additional Ti sites, the silica-titania pillared TS-1 (TS-1-PITi) provided the highest conversion among the tested catalysts; nevertheless, citronellol was oxidized over all the studied catalysts including conventional TS-1; therefore, showing that it penetrates even into MFI micropores (0.55 nm in diameter). When using acetonitrile as a solvent, the conversion was proportional to the titanium content of the catalyst. When studying the effect of the solvent, acetonitrile provided the highest epoxide selectivity (55%) while in methanol, 2-propanol and 1,4-dioxane, ring opening reactions caused epoxide decomposition.
SDS of cas: 100-51-6. About Benzyl Alcohol, If you have any questions, you can contact Aldhayan, D; Kalikova, K; Shaik, MR; Siddiqui, MRH; Prech, J or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles