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An article A Facile Approach to alpha-Keto Esters via Oxidative Esterification of alpha-Amino Carbonyl Compounds WOS:000478551000001 published article about GLYCINE DERIVATIVES; AEROBIC OXIDATION; ALCOHOLS; ACIDS; OXYGENATION; KETOESTERS; ARYLATION; PEPTIDES; AMIDES; ACETOPHENONES in [Wang, Yong-qiang; Zou, Jiao-xia; Peng, Xue; Lu, Ying-mei; Feng, Yi-yue; Chen, Chen; Shi, Tao; Wang, Zhen] Lanzhou Univ, Sch Pharm, West Donggang Rd 199, Lanzhou 730000, Gansu, Peoples R China; [Wang, Hui-hong; Wang, Zhen] Lanzhou Univ, Coll Chem & Chem Engn, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China in 2019.0, Cited 62.0. Recommanded Product: 99-93-4. The Name is 4′-Hydroxyacetophenone. Through research, I have a further understanding and discovery of 99-93-4

A direct oxidative esterification of alpha-amino carbonyl compounds by two kinds of hydroperoxides, for the synthesis of alpha-keto esters has been developed. The reaction shows broad substrates scope and good functional group tolerance, even for the synthesis of bulkyl esters, and is free of metal catalysts and external additives. Notably, the inhibitor of protein tyrosine phosphatases (PTPases) could be successfully synthesized with our protocol.

Recommanded Product: 99-93-4. About 4′-Hydroxyacetophenone, If you have any questions, you can contact Wang, YQ; Zou, JX; Wang, HH; Peng, X; Lu, YM; Feng, YY; Chen, C; Shi, T; Wang, Z or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles