128742-76-7, Chemistry is the experimental science by definition. We want to make observations to prove hypothesis. For this purpose, we perform experiments in the lab. 128742-76-7, Name is Methyl 1-methyl-1H-indole-5-carboxylate,introducing its new discovery.
Zn(OAc)2-Catalyzed C3-Carbonylacetylation of Indoles with alpha-Diazoketones Involving Wolff Rearrangement
Zn(OAc)2-catalyzed highly regioselective carbonylacetylation of indoles and pyrroles with alpha-diazoketones has been developed. This transformation involves a combination of Wolff rearrangement/cross-coupling relay and provides an efficient approach to versatile 3-carbonylacetylindoles and 2-carbonylacetylpyrroles with a broad range of functional group tolerance.
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Reference£º
Indole alkaloid derivatives as building blocks of natural products from?Bacillus thuringiensis?and?Bacillus velezensis?and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles