Application of 99409-32-2On September 30, 1992 ,《Efficient conversion of thioglycosides into glycosyl fluorides using dimethyl(methylthio)sulfonium tetrafluoroborate》 was published in Journal of Carbohydrate Chemistry. The article was written by Blomberg, Lennart; Norberg, Thomas. The article contains the following contents:
Alkyl and aryl thioglycosides, e.g., I, were converted in high yield into the corresponding α-glycosyl fluorides, e.g., II, by treatment with dimethyl(methylthio)sulfonium tetrafluoroborate. Glycosidic linkages and most protective groups are not affected by the reaction conditions. Glycosyl fluorides are proposed to be intermediates in glycosylations promoted by dimethyl(methylthio)sulfonium tetrafluoroborate. The experimental part of the paper was very detailed, including the reaction process of Ethyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-thioglucopyranoside(cas: 99409-32-2Application of 99409-32-2)
Ethyl 3,4,6-tri-O-acetyl-2-deoxy-2-phthalimido-β-D-thioglucopyranoside(cas: 99409-32-2) belongs to indole.The indole subunit is an almost ubiquitous component of biologically active natural products, and its study has been the focus of research for decades.Application of 99409-32-2They are capable of binding to a variety of receptors with high affinity and thus have applications in a wide range of therapeutic areas. Due to this activity, the indole ring system has become an important component or intermediate in the synthesis of heterocycles.
Referemce:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles