Quality Control of Bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)methane. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)methane, is researched, Molecular C19H18N2O2, CAS is 132098-59-0, about Asymmetric reduction of ketones with ruthenium-oxazoline based catalysts. Author is Debono, Nathalie; Pinel, Catherine; Jahjah, Rabih; Alaaeddine, Ali; Delichere, Pierre; Lefebvre, Frederic; Djakovitch, Laurent.
New chiral oxazoline-based ruthenium(II) complexes have been synthesized and fully characterized. The corresponding grafted catalysts were prepared by anchoring the complexes onto SiO2 or Pd/SiO2 supports. 13C CP-MAS NMR and XPS spectroscopies showed that the organometallic complexes remained unchanged when they were deposited on the support. High activity and enantioselectivity in the reduction of acetophenone were achieved with some homogeneous complexes.
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Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
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