Related Products of 138530-94-6, As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. 138530-94-6, Name is (R)-Lansoprazole, SMILES is O=[S@@](C1=NC2=CC=CC=C2N1)CC3=NC=CC(OCC(F)(F)F)=C3C, belongs to indole-building-block compound. In a article, author is Zhou, Xiao-Yu, introduce new discover of the category.
Ru-catalyzed oxidative dearomatization-hydroxylation of N-Boc indoles
Ruthenium catalyzed oxidative dearomatization-hydroxylation of N-Boc indoles for the synthesis of 2-hydroxyindolin-3-ones was described. The N-Boc indoles can be transformed into 2-hydroxyindolin-3-ones with RuCl3 center dot 3H(2)O as catalyst, p-toluenesulfonic acid (TsOH center dot H2O) as promoter and tert-butyl peroxide (TBHP, 3.0 equiv) as oxidant in acetonitrile. The mechanism had been proposed on the basis of control experiments and isolation of intermediate.
Related Products of 138530-94-6, Consequently, the presence of a catalyst will permit a system to reach equilibrium more quickly, but it has no effect on the position of the equilibrium as reflected in the value of its equilibrium constant.I hope my blog about 138530-94-6 is helpful to your research.
Reference:
Indole alkaloid derivatives as building blocks of natural products from?Bacillus thuringiensis?and?Bacillus velezensis?and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles