The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. Category: indole-building-block, 343787-29-1, Name is 1-(2-(5-(2-Methoxyethoxy)-1H-benzo[d]imidazol-1-yl)quinolin-8-yl)piperidin-4-amine, SMILES is NC1CCN(C2=C3N=C(N4C=NC5=CC(OCCOC)=CC=C45)C=CC3=CC=C2)CC1, in an article , author is Han, Xiaowei, once mentioned of 343787-29-1.
Rhodium-Catalyzed Selective C-H Trideuteromethylation of Indole at C7 Position Using Acetic-d(6) Anhydride
Rhodium-catalyzed C7-selective decarbonylative trideuteromethylation of indoles with commercially available Ac2O-d(6) via C-H and C-C bond activation has been developed. The key to the high reactivity and regioselectivity of this transformation is the appropriate choice of an indole N-(PBu2)-Bu-t chelation-assisting group. This method has many advantages, including easy access and removal of the directing group, the use of cheap and widely available deuterium methylating source, no requirement of an external ligand or oxidant, a broader substrate scope, high efficiency, and the sole regioisomer.
But sometimes, even after several years of basic chemistry education, it is not easy to form a clear picture on how they govern reactivity! 343787-29-1, you can contact me at any time and look forward to more communication. Category: indole-building-block.
Reference:
Indole alkaloid derivatives as building blocks of natural products from?Bacillus thuringiensis?and?Bacillus velezensis?and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles