In 2021.0 ANGEW CHEM INT EDIT published article about DIELS-ALDER REACTION; CATALYZED OXY-ALKYNYLATION; CHIRAL LIGANDS; ALLENECARBOXANILIDES; REARRANGEMENT; REACTIVITY in [Hari, Durga Prasad; Pisella, Guillaume; Wodrich, Matthew D.; Tsymbal, Artem, V; Waser, Jerome] Ecole Polytech Fed Lausanne, EPFL SB ISIC LCSO, Lab Catalysis & Organ Synth, BCH 1402, CH-1015 Lausanne, Switzerland; [Hari, Durga Prasad] Ecole Polytech Fed Lausanne, Inst Chem & Chem Engn, EPFL SB ISIC GE, BCH 2111, CH-1015 Lausanne, Switzerland; [Tirani, Farzaneh Fadaei; Scopelliti, Rosario] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England in 2021.0, Cited 56.0. The Name is Mequinol. Through research, I have a further understanding and discovery of 150-76-5. Safety of Mequinol
The intramolecular [4+2] cycloaddition between arenes and allenes first reported by Himbert gives rapid access to rigid polycyclic scaffolds. Herein, we report a one-pot oxyalkynylation/cycloaddition reaction proceeding under mild conditions (23-90 degrees C) and providing complex polycyclic architectures with high efficiency, and atom and step economy. The bicyclo[2.2.2]octadiene products were obtained with a wide variety of useful functional groups and were successfully applied as chiral ligands for metal catalysis. Computational studies gave a first rationalization of the low activation energy for the cycloaddition based on counter-intuitive favorable dispersive interactions in the transition state.
Safety of Mequinol. Welcome to talk about 150-76-5, If you have any questions, you can contact Hari, DP; Pisella, G; Wodrich, MD; Tsymbal, AV; Tirani, FF; Scopelliti, R; Waser, J or send Email.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles